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Atomic: M.A.C. | Reference
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Technetium
Electrons per shell 2,8,18,13,2
Electron Configuration [Kr] 4d5 5s2 open electron config
Ground state 6S5/2
Atomic Volume 8.5 cm3 mol-1
Electronegativity 1.9
Magnetic ordering No data
Mass magnetic susceptibility 3.42 x 10-8
Molar magnetic susceptibility 3.352 x 10-9
Thermal Properties
Enthalpy of Atomization 649 kJ mol-1 @25°C
Enthalpy of Fusion 23.81 kJ mol-1
Enthalpy of Vaporisation 585.22 kJ mol-1
Heat Capacity 24.27 J mol-1 K-1
Thermal Conductivity No data.
Thermal Expansion No data.
Electrical Properties
Electrical resistivity No data.
Electrical conductivity 0.067 106/cm Ω
Chemical Properties
Electrochemical Equivalent 0.51651 g Ah-1
Valence Electron Potential (-eV) 180
Ionization Potential  
First 7.28
Second 15.26
Third 29.54
Energy Levels
Kα1 (intensity 100) 18.3671 KeV
Kα2 (intensity 50) 18.2508 KeV
Kβ1 (intensity 17.4) 20.619 KeV
Kβ2 (intensity 3.8) 21.0015 KeV
Kβ3 (intensity 8) 20.5947 KeV
Lα1 (intensity 100) 2.424 KeV
Lβ1 (intensity 45) 2.5368 KeV
Lβ3 (intensity 4.5) 2.6149 KeV
Lβ4 (intensity 4) 2.5963 KeV
Lγ3 (intensity 2) 2.249 KeV
Ll (intensity 4.5) 2.1296 KeV
Atomic Radii
Empirical 135 pm
Bohr Radius 183 pm
Covalent Radius 156 pm
Van der Waals No data.
Triple covalent 110 pm
Metallic 136 pm
Oxidation States
Main Tc+4, Tc+5, Tc+7
Other Tc-1, Tc0, Tc+6
Ionisation Energies (kJ mol-1) show graph
M - M+ 702
M+ - M2+ 1472
M2+ - M3+ 2850
M3+ - M4+ 4100
M4+ - M5+ 5700
M5+ - M6+ 7300
M6+ - M7+ 9100
M7+ - M8+ 15600
M8+ - M9+ 17800
M9+ - M10+ 19900
Vapour Pressure
P (Pa) 1 10 100 1K 10K 100K
T (K) 2727 2998 3324 3726 4234 4894
Crystal Structure
Structure Hexagonal close packed
a = 273.5 pm
b = 273.5 pm
c = 438.8 pm
α = 90°
β = 90°
γ = 120°